Visible light decomposition of ammonia to N_2 with Ru(bpy)_3^2+ sensitizer
Visible light decomposition of ammonia to N_2 with Ru(bpy)_3^2+ sensitizer
Junichi Nemoto,Chihiro Harada,2 Authors,M. Kaneko
2007 · DOI: 10.1039/B611894A
Photochemical and Photobiological Sciences · 5 Citations
TLDR
In the O2 atmosphere, the oxidation of MV+* to MV2+ takes place to accumulate Ru(III) complex, so that (NH3)ox was further oxidized to N2, and the high activity of IrO2 as a cocatalyst in this system was demonstrated.